CHEMTECH INDUSTRIES INC -- CAUSTIC SODA,ANHYDROUS (1/4" FLAKE) -- 6810-00-174-6581
===================== Product Identification ===================== Product ID:CAUSTIC SODA,ANHYDROUS (1/4" FLAKE) MSDS Date:02/05/1990 FSC:6810 NIIN:00-174-6581 === Responsible Party === Company Name:CHEMTECH INDUSTRIES INC Address:9909 CLAYTON RD City:ST LOUIS State:MO ZIP:63124 Country:US Info Phone Num:314-966-9900 Emergency Phone Num:314-966-9900 CAGE:56894 === Contractor Identification === Company Name:CHEMTECH INDUSTRIES INC MANUFACTURED PRODUCTS DIV Address:1655 DES PERES RD Box:31000 City:ST. LOUIS State:MO ZIP:63131-1821 Country:US Phone:314-966-9934 CAGE:56894 ============= Composition/Information on Ingredients ============= Ingred Name:SODIUM HYDROXIDE (SARA III) CAS:1310-73-2 RTECS #:WB4900000 Fraction by Wt: > 96% Other REC Limits:NONE SPECIFIED OSHA PEL:2 MG/M3 ACGIH TLV:C 2 MG/M3; 9293 EPA Rpt Qty:1000 LBS DOT Rpt Qty:1000 LBS ===================== Hazards Identification ===================== LD50 LC50 Mixture:LD50 (ORAL, RAT) IS 100-200 MG/KG Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO Health Hazards Acute and Chronic:ACUTE-INHALATION:DUST IS VERY IRRITATING TO THE UPPER RESPIRATORY TRACT.PROLONGED EXPOSURE MAY CAUSE BURNS.EYES/SKIN:CAUSES SEVERE BURNS.INGESTION:HARMFUL/FATAL IF SWALLOWED.CAUSES SEVERE BURNS,SEVERE PAIN,VOMITING,DIARRHEA & SHOCK.CHRONIC-MAY CAUSE BLISTERS/DERMATITIS. Effects of Overexposure:INHALING DUST IS VERY IRRITATING TO THE UPPER RESPIRATORY TRACT. PROLONGED EXPOSURE MAY CAUSE BURNS. PRODUCT CAUSES SEVERE BURNS TO EYES & SKIN. HARMFUL OR FATAL IF SWALLOWED. CAUSES SEVERE BURNS, SEV ERE PAIN, VOMITING, DIARRHEA AND SHOCK. Medical Cond Aggravated by Exposure:PRE-EXISTING SKIN DISORDERS MAY BE MORE SUSCEPTIBLE TO THIS MATERIAL. ======================= First Aid Measures ======================= First Aid:GET IMMEDIATE MEDICAL ATTENTION.EYE:IMMEDIATELY FLUSH WITH WATER FOR 15 MINUTES,HOLDING EYELIDS OPEN.SKIN:WASH WITH SOAP & WATER.INHALATION:REMOVE TO FRESH AIR.TREAT SYMPTOMATICALLY.INGESTION:DO NOT I NDUCE VOMITING.IF CONSCIOUS,DRINK ONE GLASS OF MILK/WATER.CALL A PHYSICIAN/POISON CONTROL CENTER IMMEDIATELY. ===================== Fire Fighting Measures ===================== Flash Point:NONE Extinguishing Media:USE MEDIA APPROPRIATE FOR SURROUNDING FIRE. USE WATER WITH CAUTION AND IN FLOODING AMOUNT. REACTS WITH WATER. Fire Fighting Procedures:WEAR FIRE FIGHTING PROTECTIVE EQUIPMENT AND A FULL FACED SELF CONTAINED BREATHING APPARATUS OR A NIOSH-APPROVED DUST RESPIRATOR. Unusual Fire/Explosion Hazard:REACTION WITH METAL GENERATES FLAMMABLE HYDROGEN GAS. CONTACT WITH MOISTURE/WATER MAY GENERATE SUFFICIENT HEAT TO IGNITE NEARBY COMBUSTIBLE MATERIALS. ================== Accidental Release Measures ================== Spill Release Procedures:IF POWDER, SWEEP UP AND TRANSFER TO PROPER CONTAINER FOR DISPOSAL. AVOID BREATHING THE DUST. IF LIQUID, NEUTRALIZE WITH WEAK ACID. AVOID FROTHING. FLUSH TO SEWER WITH LARGE AMOUNT OF WATER. Neutralizing Agent:DILUTE ACID ====================== Handling and Storage ====================== Handling and Storage Precautions:STORAGE-KEEP CONTAINER TIGHTLY CLOSED AWAY FROM MOISTURE & ACIDS. Other Precautions:USE D.O.T. "CORROSIVE" LABEL IN ADDITION TO COMMODITY LABEL. MATERIAL IS CORROSIVE TO EYES, SKIN AND MUCOUS MEMBRANES. AVOID CONTACT IN ALL FORMS. AVOID BREATHING THE DUST. CONSIDERABLE HEAT IS GENERA TED WHEN IT IS DISSOLVED IN WATER. ============= Exposure Controls/Personal Protection ============= Respiratory Protection:A NIOSH-APPROVED DUST RESPIRATOR SHOULD BE WORN IF NEEDED. IF RESPIRATORS ARE USED, A PROGRAM SHOULD BE INSTITUTED TO ASSURE COMPLIANCE WITH OSHA STANDARD 29CFR 1910.134. Ventilation:GOOD GENERAL VENTILATION SHOULD BE SUFFICIENT. Protective Gloves:RUBBER OR PLASTIC Eye Protection:SAFETY GLASSES WITH SIDE SHIELD Other Protective Equipment:EYE WASH STATION, SAFETY SHOWER, RUBBER BOOTS AND APRONS Work Hygienic Practices:WASH THOROUGHLY AFTER HANDLING AND BEFORE EATING, DRINKING OR SMOKING. Supplemental Safety and Health ================== Physical/Chemical Properties ================== HCC:B1 Boiling Pt:B.P. Text:2534F,1390C Melt/Freeze Pt:M.P/F.P Text:604F,318C Spec Gravity:2.13 Solubility in Water:APPRECIABLE Appearance and Odor:WHITE SOLID, GRANULAR OR FLAKES, PRACTICALLY ODORLESS. Percent Volatiles by Volume:NONE ================= Stability and Reactivity Data ================= Stability Indicator/Materials to Avoid:YES ALUMINUM, TIN, LEAD, ZINC AND THEIR ALLOYS, ALL ACIDS. DISSOLVES IN WATER RELEASING HEAT. Stability Condition to Avoid:NONE Hazardous Decomposition Products:AQUEOUS SOLUTIONS MAY LIBERATE HYDROGEN UPON REACTION WITH METALS LISTED ABOVE. ==================== Disposal Considerations ==================== Waste Disposal Methods:DISCHARGE, TREATMENT OR DISPOSAL MAY BE SUBJECT TO FEDERAL, STATE OR LOCAL REGULATIONS. Disclaimer (provided with this information by the compiling agencies): This information is formulated for use by elements of the Department of Defense. The United States of America in no manner whatsoever, expressly or implied, warrants this information to be accurate and disclaims all liability for its use. Any person utilizing this document should seek competent professional advice to verify and assume responsibility for the suitability of this information to their particular situation.